The first step is to install the Purchase Orders for WooCommerce plugin https://en-nz.wordpress.org/plugins/purchase-orders-for-woocommerce/. This enables the PO number and any other details such as name and address to be captured at checkout – The settings for this are found under WooCommerce/Settings/Payments.
The PO number will then appear in the order and also in the invoice. At present Xero doesn’t permit custom fields so the information is presented as a line item on the invoice. The PO number can also be used as the invoice reference.
And with the PO number in the invoice reference box:
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